Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
443 5 |
Ultima descărcare din IBN: 2024-03-15 14:12 |
Căutarea după subiecte similare conform CZU |
547.057 (5) |
Органическая химия (484) |
SM ISO690:2012 DAS, Aparna, BANIK, Bimal Krishna, YADAV, Ram Naresh. Microwave-induced conversion of electromagnetic energy into heat energy in different solvents: synthesis of β-lactams. In: Chemistry Journal of Moldova, 2022, nr. 1(17), pp. 62-66. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2021.864 |
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Chemistry Journal of Moldova | ||||||
Numărul 1(17) / 2022 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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DOI:https://doi.org/10.19261/cjm.2021.864 | ||||||
CZU: 547.057 | ||||||
Pag. 62-66 | ||||||
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This article describes the effect of loss tangent (tanδ) values of the solvents in the stereospecific synthesis of optically active cis β-lactams under diverse microwave-induced conditions. The effects of low tanδ values of the solvents are found to be more crucial than solvents with high dipole moments and dielectric constants. Although, a significant progress of microwave-induced reactions has been registered lately, no reports have examined the tanδ values of the solvents in reactions conducted in a microwave. In this study, the synthesis of hydroxy-β-lactams under microwave irradiation with diverse solvents was considered by focusing on their tanδ values. The results indicated that for the synthesis of β-lactams solvents with low tanδ and high dipole moment and high dielectric constant are necessary. Compared to DMSO (tanδ= 0.82) and DMF (tanδ= 0.16), dichloroethane (tanδ= 0.12), dichloromethane (tanδ= 0.04) and tetrahydrofuran (tanδ= 0.04) are observed to be more effective. |
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Cuvinte-cheie β-lactam, loss tangent, microwave, stereospecific, optically active |
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