One-pot and solvent-free synthesis of carbodiimide modified chitosan; extraordinary thermal stability
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2023-12-29 09:46
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54.057+66.01 (1)
Получение, выделение, синтез, очистка и т.п. (51)
Химическая технология. Химическая промышленность. Родственные отрасли (1504)
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DAS, Silvadas Jesna, SIDHARTH, Mohan, SIMI, Chandroth Kalyad. One-pot and solvent-free synthesis of carbodiimide modified chitosan; extraordinary thermal stability. In: Chemistry Journal of Moldova, 2022, nr. 1(17), pp. 56-61. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2022.895
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Chemistry Journal of Moldova
Numărul 1(17) / 2022 / ISSN 1857-1727 /ISSNe 2345-1688

One-pot and solvent-free synthesis of carbodiimide modified chitosan; extraordinary thermal stability

DOI:https://doi.org/10.19261/cjm.2022.895
CZU: 54.057+66.01

Pag. 56-61

Das Silvadas Jesna, Sidharth Mohan, Simi Chandroth Kalyad
 
Mahatma Gandhi College
 
 
Disponibil în IBN: 13 iulie 2022


Rezumat

A facile, one-pot, and solvent-free synthesis is demonstrated to obtain a thermally stable chitosan biopolymer. In this work, a bifunctional isocyanate molecule is reacted with chitosan to form urea and urethane bonds between chitosan chains. Subsequently, the designed chemistry facilitated the formation of carbodiimide bonds between chitosan chains via dehydration of the urea bond. The modified chitosan is superior in thermal properties with T10%> 400°C and char yield of 65%. The modified chitosan can be used as a thermally stable bio-filler. This synthetic methodology is a facile route to achieve improved thermal stability in biopolymers

Cuvinte-cheie
chitosan, one-pot synthesis, carbodiimide, porous morphology, thermal stability