Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
455 9 |
Ultima descărcare din IBN: 2023-12-29 09:46 |
Căutarea după subiecte similare conform CZU |
54.057+66.01 (1) |
Получение, выделение, синтез, очистка и т.п. (51) |
Химическая технология. Химическая промышленность. Родственные отрасли (1504) |
SM ISO690:2012 DAS, Silvadas Jesna, SIDHARTH, Mohan, SIMI, Chandroth Kalyad. One-pot and solvent-free synthesis of carbodiimide modified chitosan; extraordinary thermal stability. In: Chemistry Journal of Moldova, 2022, nr. 1(17), pp. 56-61. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2022.895 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Chemistry Journal of Moldova | ||||||
Numărul 1(17) / 2022 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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DOI:https://doi.org/10.19261/cjm.2022.895 | ||||||
CZU: 54.057+66.01 | ||||||
Pag. 56-61 | ||||||
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Rezumat | ||||||
A facile, one-pot, and solvent-free synthesis is demonstrated to obtain a thermally stable chitosan biopolymer. In this work, a bifunctional isocyanate molecule is reacted with chitosan to form urea and urethane bonds between chitosan chains. Subsequently, the designed chemistry facilitated the formation of carbodiimide bonds between chitosan chains via dehydration of the urea bond. The modified chitosan is superior in thermal properties with T10%> 400°C and char yield of 65%. The modified chitosan can be used as a thermally stable bio-filler. This synthetic methodology is a facile route to achieve improved thermal stability in biopolymers |
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Cuvinte-cheie chitosan, one-pot synthesis, carbodiimide, porous morphology, thermal stability |
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