Temperature and volume dependence of thermal conductivity in solid CHCl3
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PURSKY, O., KONSTANTINOV, V.. Temperature and volume dependence of thermal conductivity in solid CHCl3. In: Moldavian Journal of the Physical Sciences, 2007, nr. 1(6), pp. 72-78. ISSN 1810-648X.
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Moldavian Journal of the Physical Sciences
Numărul 1(6) / 2007 / ISSN 1810-648X /ISSNe 2537-6365

Temperature and volume dependence of thermal conductivity in solid CHCl3

Pag. 72-78

Pursky O.1, Konstantinov V.2
 
1 Taras Shevchenko National University of Kyiv,
2 B.Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine
 
 
Disponibil în IBN: 19 noiembrie 2013


Rezumat

The temperature and volume dependences of the thermal conductivity of solid CHCl3 are described in the framework of a model, where the heat is transferred by phonons and above the phonon mobility edge by “diffusive” modes migrating randomly from site to site. The mobility edge ωo is determined from the condition, that the phonon mean free path restricted by the Umklapp processes cannot become smaller than half the phonon wavelength. Significant deviations from the dependence Λ∝1/T are explained by the thermal conductivity approaching its lower limit.