Characterizations of pure and eu-doped ZnO aerogels nanostructures elaborated by a modified sol gel process
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BEDHOUCHE, Fatiha, DJOUADI, Djamel, SOUALAH, Ahcane, CHELOUCHE, Azeddine, TOUAM, Tahar. Characterizations of pure and eu-doped ZnO aerogels nanostructures elaborated by a modified sol gel process. In: Moldavian Journal of the Physical Sciences, 2023, nr. 1, pp. 63-74. ISSN 1810-648X. DOI: https://doi.org/10.53081/mjps.2023.22-1.04
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Moldavian Journal of the Physical Sciences
Numărul 1 / 2023 / ISSN 1810-648X /ISSNe 2537-6365

Characterizations of pure and eu-doped ZnO aerogels nanostructures elaborated by a modified sol gel process

DOI:https://doi.org/10.53081/mjps.2023.22-1.04
CZU: 53.043

Pag. 63-74

Bedhouche Fatiha1, Djouadi Djamel1, Soualah Ahcane1, Chelouche Azeddine1, Touam Tahar2
 
1 University of Bejaia,
2 Université Badji Mokhtar-Annaba
 
 
Disponibil în IBN: 31 decembrie 2023


Rezumat

Herein we report on the structural and optical properties of pure and Eu-doped (3% at.) ZnO aerogels nanostructures (ZnO-ans) synthesized by sol-gel associated with drying at supercritical conditions of isopropanol (254 °C, 54 bars). The samples were investigated using X-ray diffraction (XRD), SEM, UV-visible spectroscopy, FTIR and photoluminescence (PL). XRD studies exhibit the formation of a high crystal quality ZnO wurtzite hexagonal structure. The UV-visible measurements point out that the absorption intensity and the band gap energy increase after Eu-doping. FTIR analysis confirms the formation of ZnO phase and reveals a shift toward longer wavenumber of the Zn-O absorption band after Eu -doping. SEM images show that Eu3+ ions lead to change the morphology of ZnO crystalline from pastille to sphere. PL measurements reveal a decrease of UV luminescence intensity and an increase of the visible one due to Eu-doping.

Cuvinte-cheie
ZnO, Eu-doping, supercritical isopropanol, structure, morphology, photoluminescence.