Effect of Heteronuclear Salicylate Complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n on Corrosion of Steel St. 3 in Water
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PARSHUTIN, Vladimir, KOVAL, Andrei, GORINCHOY, Viorina, LOZAN, Vasile. Effect of Heteronuclear Salicylate Complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n on Corrosion of Steel St. 3 in Water. In: Surface Engineering and Applied Electrochemistry, 2024, vol. 60, pp. 109-121. ISSN 1068-3755. DOI: https://doi.org/10.3103/S1068375524010137
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Surface Engineering and Applied Electrochemistry
Volumul 60 / 2024 / ISSN 1068-3755 /ISSNe 1934-8002

Effect of Heteronuclear Salicylate Complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n on Corrosion of Steel St. 3 in Water

DOI:https://doi.org/10.3103/S1068375524010137

Pag. 109-121

Parshutin Vladimir1, Koval Andrei1, Gorinchoy Viorina2, Lozan Vasile2
 
1 Institute of Applied Physics, MSU,
2 Institute of Chemistry, MSU
 
 
Disponibil în IBN: 2 aprilie 2024


Rezumat

The corrosion process of steel St. 3 in water with the addition of a heteronuclear salicylate complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n by gravimetric, electrochemical, and physicochemical methods (X‑ray phase analysis, UV, IR and Mössbauer spectroscopy) has been studied. It has been shown that the introduction of the additive under study into a corrosive environment significantly reduces steel corrosion. Depending on the duration of the tests and the concentration of the inhibitor, the corrosion rate is reduced by 5.1–11.1 times with a degree of protection of 80.5–91.0%. A mechanism of inhibition has been proposed. The inclusion of products of interaction of ionized iron with the complex in the coating layers has been proven.

Cuvinte-cheie
Coating layer, Corrosion of steel, Corrosion of steel St 3, Corrosion process, Gravimetric methods, Heteronuclear, Heteronuclear salicylate complex, inhibitor, Mossbauer spectra, Protective coating layer